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Date of Issue : Feb 1997 1. IDENTIFICATION
General Product Name : IRON OXIDE RED Other Names : IRON OXIDE RED UN No. : N/A Dangerous Goods Class : N/A Subsidiary Risk : None Allocated Hazchem Code : N/A Pack Group : 0 EPG : N/A Poisons Schedule : N/A Uses : Colouring of many end-products.
1.1 Physical Description / Properties
Appearance : Red powder, odourless. Formula : Fe2O3 Boiling Point : N/A deg C Melting Point : >1000 deg C Vapour Pressure : N/A Specific Gravity : 5 (water = 1) Flash Point : N/A pH : 5-8 (50 g/L) Solubility in water : Insol g/l (25 deg C) Flammability Limits (as percentage volume in air) Lower Explosion Limit : N/A Upper Explosion Limit : N/A 1.2 Other Properties
Density : approx 5 g/cm3 @ 20 deg C Bulk density : 600-1000 kg/m3 @ 20 deg C 1.3 Ingredients
2. HEALTH HAZARD INFORMATION
2.1 Health Effects - Acute Swallowed
No significant health effects could be found. Eye
Mechanical action arising from eye contact (action of dust) may cause slight temporary irritation of the mucosa. Skin
Slightly irritative. Inhaled
Irritant to mucous membranes and the respiratory tract. 2.2 Health Effects - Chronic
According to the present state of knowledge this pigment is physiologically harmless; under extreme conditions, however, mechanical action arising from eye contact (action of dust) may cause slight temporary irritation of the mucosa.
2.3 First Aid
Swallowed
If symptoms occur seek medical attention.
Eye
In case of eye contact rinse with plenty of water. If irritation of the eyes persists, consult a doctor (ophthalmologist).
Skin
Wash affected areas thoroughly with mild soap and water.
Inhaled
Remove from contaminated area immediately, avoid becoming a casualty. If NOT breathing apply artificial resuscitation.
First Aid Facilities
Ensure an eye bath and safety shower are available and ready for use.
2.5 Advice to Doctor
Treat symptomatically based on judgement of doctor and individual reactions of patient.
2.6 Toxicity Data
Toxicological tests on chemically identical products yielded the following results : Oral LD50 = >5000 mg/kg (Rat)
3. PRECAUTIONS FOR USE
3.1 Exposure Standards
No exposure standard has been established for this particular material, however the following is recommended for nuisance dust : TWA 10 mg/m3 (total dust) or 5 mg/m3 (respirable dust).
3.2 Engineering Controls
Ensure workplace is well ventilated to maintain airborne concentrations below standards.
3.3 Personal Protection
Eye protection : goggles Respiratory protection : dust-protection mask if the exposure limit is exceeded. Wash hands and face thoroughly after handling and before work breaks, eating, drinking, smoking and using toilet facilities.
3.4 Flammability
Material is non-flammable SAFE HANDLING INFORMATION
4.1 Storage / Transport
Store in a cool dry place. No special measures required. Keep separated from foodstuffs.
4.2 Packaging / Labelling UN No. N/A Class N/A Sub Risk None Allocated Hazchem Code N/A Pack Group 0 EPG No. N/A Shipping Name IRON OXIDE RED Hazard
Risk Phrases
Safety Phrases
4.3 Spills and Disposal
Spills
Avoid raising dust. Clean-up personnel should wear protective clothing including breathing apparatus/dust mask.
Disposal
May be disposed of in approved landfills provided local regulations are observed
4.4 FIRE AND EXPLOSION HAZARD Fire / Explosion
Thermal decomposition : no decomposition when used as directed. Hazardous decomposition products : not applicable. Hazardous reactions : no hazardous reactions observed.
Extinguishing Media
Use equipment/media appropriate to surrounding fire conditions. No restriction in fire conditions. 5 OTHER INFORMATION
Other Information
Ecotoxicological tests on chemically identical products yielded the following results : Acute fish toxicity : Golden orfe (Leuciscus idus) LCo > 1000 mg/L Acute bacterial toxicity : No harmful effect on Pseudomonas putida > 1000 mg/L As the product is practically insoluble in water, it is separated in almost any filtration and sedimentation process.
5.1 Contact Points
Date of Issue : Feb 1997 1. IDENTIFICATION
General
Product Name : IRON OXIDE YELLOW
Other Names : IRON OXIDE YELLOW
UN No. : N/A
Dangerous Goods Class : N/A
Subsidiary Risk : None Allocated
Hazchem Code : N/A
Pack Group : 0
EPG : N/A
Poisons Schedule : N/A
Uses :
Colouring of many end-products.
1.1 Physical Description / Properties
Appearance : Yellow powder, odourless.
Formula : FeOOH
Boiling Point : N/A deg C
Melting Point : >1000 deg C
Vapour Pressure : N/A
Specific Gravity : 4.1 (water = 1)
Flash Point : N/A
pH : 3.5-7.5 (50 g/L)
Solubility in water : Insol g/l (25 deg C)
Flammability Limits (as percentage volume in air)
Lower Explosion Limit : N/A
Upper Explosion Limit : N/A
1.2 Other Properties
Density : approx 4.1 g/cm3 @ 20 deg C Bulk density : 200-400 kg/m3 @ 20 deg C 1.3 Ingredients
2. HEALTH HAZARD INFORMATION
2.1 Health Effects - Acute Swallowed
No significant health effects could be found. Eye
Mechanical action arising from eye contact (action of dust) may cause slight temporary irritation of the mucosa. Skin
Slightly irritative. Inhaled
Irritant to mucous membranes and the respiratory tract. 2.2 Health Effects - Chronic
According to the present state of knowledge this pigment is physiologically harmless; under extreme conditions, however, mechanical action arising from eye contact (action of dust) may cause slight temporary irritation of the mucosa.
2.3 First Aid
Swallowed
If symptoms occur seek medical attention.
Eye
In case of eye contact rinse with plenty of water. If irritation of the eyes persists, consult a doctor (ophthalmologist).
Skin
Wash affected areas thoroughly with mild soap and water.
Inhaled
Remove from contaminated area immediately, avoid becoming a casualty. If NOT breathing apply artificial resuscitation.
First Aid Facilities
Ensure an eye bath and safety shower are available and ready for use.
2.5 Advice to Doctor
Treat symptomatically based on judgement of doctor and individual reactions of patient.
2.6 Toxicity Data
Toxicological tests on chemically identical products yielded the following results : Oral LD50 = >5000 mg/kg (Rat)
3. PRECAUTIONS FOR USE
3.1 Exposure Standards
No exposure standard has been established for this particular material, however the following is recommended for nuisance dust : TWA 10 mg/m3 (total dust) or 5 mg/m3 (respirable dust).
3.2 Engineering Controls
Ensure workplace is well ventilated to maintain airborne concentrations below standards.
3.3 Personal Protection
Eye protection : goggles Respiratory protection : dust-protection mask if the exposure limit is exceeded. Wash hands and face thoroughly after handling and before work breaks, eating, drinking, smoking and using toilet facilities.
3.4 Flammability
Material is non-flammable SAFE HANDLING INFORMATION
4.1 Storage / Transport
Store in a cool dry place. No special measures required. Keep separated from foodstuffs.
4.2 Packaging / Labelling UN No. N/A Class N/A Sub Risk None Allocated Hazchem Code N/A Pack Group 0 EPG No. N/A Shipping Name IRON OXIDE YELLOW Hazard
Risk Phrases
Safety Phrases
4.3 Spills and Disposal
Spills
Avoid raising dust. Clean-up personnel should wear protective clothing including breathing apparatus/dust mask.
Disposal
May be disposed of in approved landfills provided local regulations are observed
4.4 FIRE AND EXPLOSION HAZARD Fire / Explosion
Thermal decomposition : from approx 180 deg C conversion into Fe2O3. Hazardous decomposition products : no hazardous decomposition products observed. Hazardous reactions : no hazardous reactions observed.
Extinguishing Media
Use equipment/media appropriate to surrounding fire conditions. No restriction in fire conditions. 5 OTHER INFORMATION
Other Information
Ecotoxicological tests on chemically identical products yielded the following results : Acute fish toxicity : Golden orfe (Leuciscus idus) LCo > 1000 mg/L Acute bacterial toxicity : No harmful effect on Pseudomonas putida > 1000 mg/L As the product is practically insoluble in water, it is separated in almost any filtration and sedimentation process.
5.1 Contact Points
Date of Issue : Feb 1997 1. IDENTIFICATION
General
Product Name : IRON OXIDE BLACK
Other Names : IRON OXIDE BLACK
UN No. : N/A
Dangerous Goods Class : N/A
Subsidiary Risk : None Allocated
Hazchem Code : N/A
Pack Group : 0
EPG : N/A
Poisons Schedule : N/A
Uses :
Colouring of many end-products.
1.1 Physical Description / Properties
Appearance : Black powder, odourless.
Formula : Fe3O4
Boiling Point : N/A deg C
Melting Point : >1000 deg C
Vapour Pressure : N/A
Specific Gravity : 4.6 (water = 1)
Flash Point : N/A
pH : 4-8 (50 g/L)
Solubility in water : Insol g/l (25 deg C)
Flammability Limits (as percentage volume in air)
Lower Explosion Limit : N/A
Upper Explosion Limit : N/A
1.2 Other Properties
Density : approx 4.6 g/cm3 @ 20 deg C Bulk density : 600-800 kg/m3 @ 20 deg C 1.3 Ingredients
2. HEALTH HAZARD INFORMATION
2.1 Health Effects - Acute Swallowed
No significant health effects could be found. Eye
Mechanical action arising from eye contact (action of dust) may cause slight temporary irritation of the mucosa. Skin
Slightly irritative. Inhaled
Irritant to mucous membranes and the respiratory tract. 2.2 Health Effects - Chronic
According to the present state of knowledge this pigment is physiologically harmless; under extreme conditions, however, mechanical action arising from eye contact (action of dust) may cause slight temporary irritation of the mucosa.
2.3 First Aid
Swallowed
If symptoms occur seek medical attention.
Eye
In case of eye contact rinse with plenty of water. If irritation of the eyes persists, consult a doctor (ophthalmologist).
Skin
Wash affected areas thoroughly with mild soap and water.
Inhaled
Remove from contaminated area immediately, avoid becoming a casualty. If NOT breathing apply artificial resuscitation.
First Aid Facilities
Ensure an eye bath and safety shower are available and ready for use.
2.5 Advice to Doctor
Treat symptomatically based on judgement of doctor and individual reactions of patient.
2.6 Toxicity Data
Toxicological tests on chemically identical products yielded the following results : Oral LD50 = >5000 mg/kg (Rat)
3. PRECAUTIONS FOR USE
3.1 Exposure Standards
No exposure standard has been established for this particular material, however the following is recommended for nuisance dust : TWA 10 mg/m3 (total dust) or 5 mg/m3 (respirable dust).
3.2 Engineering Controls
Ensure workplace is well ventilated to maintain airborne concentrations below standards.
3.3 Personal Protection
Eye protection : goggles Respiratory protection : dust-protection mask if the exposure limit is exceeded. Wash hands and face thoroughly after handling and before work breaks, eating, drinking, smoking and using toilet facilities.
3.4 Flammability
Material is non-flammable SAFE HANDLING INFORMATION
4.1 Storage / Transport
Store in a cool dry place. No special measures required. Keep separated from foodstuffs.
4.2 Packaging / Labelling UN No. N/A Class N/A Sub Risk None Allocated Hazchem Code N/A Pack Group 0 EPG No. N/A Shipping Name IRON OXIDE BLACK Hazard
Risk Phrases
Safety Phrases
4.3 Spills and Disposal
Spills
Avoid raising dust. Clean-up personnel should wear protective clothing including breathing apparatus/dust mask.
Disposal
May be disposed of in approved landfills provided local regulations are observed
4.4 FIRE AND EXPLOSION HAZARD Fire / Explosion
Thermal decomposition : from approx. 80 deg C oxidation and conversion to Fe2O3. Hazardous decomposition products : no hazardous decomposition products observed. Hazardous reactions : no hazardous reactions observed.
Extinguishing Media
Use equipment/media appropriate to surrounding fire conditions. No restriction in fire conditions. 5 OTHER INFORMATION
Other Information
Ecotoxicological tests on chemically identical products yielded the following results : Acute fish toxicity : Golden orfe (Leuciscus idus) LCo > 1000 mg/L Acute bacterial toxicity : No harmful effect on Pseudomonas putida > 1000 mg/L As the product is practically insoluble in water, it is separated in almost any filtration and sedimentation process.
5.1 Contact Points
Date of Issue : Feb 1997 1. IDENTIFICATION
General
Product Name : IRON OXIDE BROWN
Other Names : IRON OXIDE BROWN
UN No. : N/A
Dangerous Goods Class : N/A
Subsidiary Risk : None Allocated
Hazchem Code : N/A
Pack Group : 0
EPG : N/A
Poisons Schedule : N/A
Uses :
Colouring of many end-products.
1.1 Physical Description / Properties
Appearance : Brown powder, odourless.
Formula : mixture of Fe2O3, Fe3O4 and FeOOH
Boiling Point : N/A deg C
Melting Point : >1000 deg C
Vapour Pressure : N/A
Specific Gravity : 4.4 (water = 1)
Flash Point : N/A
pH : 4-7 (50 g/L)
Solubility in water : Insol g/l (25 deg C)
Flammability Limits (as percentage volume in air)
Lower Explosion Limit : N/A
Upper Explosion Limit : N/A
1.2 Other Properties
Density : approx 4.4 g/cm3 @ 20 deg C Bulk density : 500-700 kg/m3 @ 20 deg C 1.3 Ingredients
2. HEALTH HAZARD INFORMATION
2.1 Health Effects - Acute Swallowed
No significant health effects could be found. Eye
Mechanical action arising from eye contact (action of dust) may cause slight temporary irritation of the mucosa. Skin
Slightly irritative. Inhaled
Irritant to mucous membranes and the respiratory tract. 2.2 Health Effects - Chronic
According to the present state of knowledge this pigment is physiologically harmless; under extreme conditions, however, mechanical action arising from eye contact (action of dust) may cause slight temporary irritation of the mucosa.
2.3 First Aid
Swallowed
If symptoms occur seek medical attention.
Eye
In case of eye contact rinse with plenty of water. If irritation of the eyes persists, consult a doctor (ophthalmologist).
Skin
Wash affected areas thoroughly with mild soap and water.
Inhaled
Remove from contaminated area immediately, avoid becoming a casualty. If NOT breathing apply artificial resuscitation.
First Aid Facilities
Ensure an eye bath and safety shower are available and ready for use.
2.5 Advice to Doctor
Treat symptomatically based on judgement of doctor and individual reactions of patient.
2.6 Toxicity Data
Toxicological tests on chemically identical products yielded the following results : Oral LD50 = >5000 mg/kg (Rat)
3. PRECAUTIONS FOR USE
3.1 Exposure Standards
No exposure standard has been established for this particular material, however the following is recommended for nuisance dust : TWA 10 mg/m3 (total dust) or 5 mg/m3 (respirable dust).
3.2 Engineering Controls
Ensure workplace is well ventilated to maintain airborne concentrations below standards.
3.3 Personal Protection
Eye protection : goggles Respiratory protection : dust-protection mask if the exposure limit is exceeded. Wash hands and face thoroughly after handling and before work breaks, eating, drinking, smoking and using toilet facilities.
3.4 Flammability
Material is non-flammable SAFE HANDLING INFORMATION
4.1 Storage / Transport
Store in a cool dry place. No special measures required. Keep separated from foodstuffs.
4.2 Packaging / Labelling UN No. N/A Class N/A Sub Risk None Allocated Hazchem Code N/A Pack Group 0 EPG No. N/A Shipping Name IRON OXIDE BROWN Hazard
Risk Phrases
Safety Phrases
4.3 Spills and Disposal
Spills
Avoid raising dust. Clean-up personnel should wear protective clothing including breathing apparatus/dust mask.
Disposal
May be disposed of in approved landfills provided local regulations are observed
4.4 FIRE AND EXPLOSION HAZARD Fire / Explosion
Thermal decomposition : from approx 120 deg C oxidation and conversion to Fe2O3. Hazardous decomposition products : no hazardous decomposition products observed. Hazardous reactions : no hazardous reactions observed.
Extinguishing Media
Use equipment/media appropriate to surrounding fire conditions. No restriction in fire conditions. 5 OTHER INFORMATION
Other Information
Ecotoxicological tests on chemically identical products yielded the following results : Acute fish toxicity : Golden orfe (Leuciscus idus) LCo > 1000 mg/L Acute bacterial toxicity : No harmful effect on Pseudomonas putida > 1000 mg/L As the product is practically insoluble in water, it is separated in almost any filtration and sedimentation process.
5.1 Contact Points
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The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume no liability resulting from its use.
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